Syntheses and Structures of (MCl(NN)(dpt))2+(M=Co, Rh; NN=bpy, phen) Complexes.
نویسندگان
چکیده
منابع مشابه
Syntheses and structures of terminal arylalumylene complexes.
Terminal arylalumylene complexes of platinum [Ar-Al-Pt(PCy3 )2 ] (Ar=2,6-[CH(SiMe3 )2 ]2 C6 H3 (Bbp) or 2,6-[CH(SiMe3 )2 ]2 -4-(tBu)C6 H2 (Tbb)) have been synthesized either by the reaction of a dialumene-benzene adduct with [Pt(PCy3 )2 ], or by the reduction of 1,2-dibromodialumanes Ar(Br)Al-Al(Br)Ar in the presence of [Pt(PCy3 )2 ]. X-Ray crystallographic analysis reveals that the AlPt bond ...
متن کاملCopper ( I ) - Purine - Phosphine Complexes . Syntheses and Molecular Structures of [
The syntheses and molecular structures of two novel polynuclear copper(I)-purine-phosphine complexes are reported. The first one is a dinuclear [Cu2(μ-HL)2(μ-dppm)(η-dppm)2] complex (H2L is 8-mercaptotheophylline). The compound crystallizes in the triclinic system, space group P1h, with cell constants a ) 12.342(5) Å, b ) 15.255(5) Å, c ) 24.972(5) Å, R ) 74.31(2)°, â ) 78.62(2)°, γ ) 72.51(2)°...
متن کاملLithium, sodium and potassium picolyl complexes: syntheses, structures and bonding.
Synthetically important for introducing a picolyl scaffold into a molecular construction, alkali metallated picoline (methylpyridine) complexes are also interesting in their own right for the diversity of their ligand-metal bonding possibilities. Here the syntheses of seven new such complexes are reported: namely three 4-picoline derivatives 4-picLi·Me6TREN, 1, 4-picNa·Me6TREN, 2, and [4-picK·2...
متن کاملChromophore-labelled, luminescent platinum complexes: syntheses, structures, and spectroscopic properties.
Ligands based upon 4-carboxamide-2-phenylquinoline derivatives have been synthesised with solubilising octyl hydrocarbon chains and tethered aromatic chromophores to give naphthyl (), anthracenyl () and pyrenyl () ligand variants, together with a non-chromophoric analogue () for comparison. (1)H NMR spectroscopic studies of the ligands showed that two non-interchangeable isomers exist for and w...
متن کاملGold (I) Complexes of 2,2'-Biimidazolate Ligand: Syntheses and Spectral Properties of Hetero-polymetallic Complexes Having Ru2Au2 Core
The reaction of [Ru(L)2(H2biim)](ClO4)2 [L1 = 2,2¢-bipyridine (bpy) or L2 = 2-(phenylazo)pyridine (pap) and H2biim = 2,2¢-biimidazole] with Au(tht)Cl (tht = tetrahydrothiophene) in presence of base in methanol produced a terametallic cationic complex [{Ru(L)2(biim)}<s...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1994
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1994.39